Magnetism and site occupancy in epitaxial Y-rich yttrium iron garnet films
نویسندگان
چکیده
Y-rich yttrium iron garnet (Y-YIG) thin films were grown on gadolinium gallium substrates using pulsed laser deposition from a ${\mathrm{YFeO}}_{3}$ target. The are epitaxial the substrate, and unit cell of (001)- (111)-oriented Y-YIG undergoes tetragonal or rhombohedral distortion, respectively. has lower room temperature magnetization but higher low-temperature than bulk YIG, its Curie was in range 330--400 K, depending growth conditions. First-principles calculations predict that ${\mathrm{Y}}_{\mathrm{Fe}}$ antisite defects more stable octahedral tetrahedral Fe sites. Temperature-dependent measurements together with superexchange dilution model composition determined x-ray photoelectron spectroscopy indicate nonmagnetic species (${\mathrm{Y}}^{3+}$ vacancies) predominantly accommodated sites, there is significant occupancy
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ژورنال
عنوان ژورنال: Physical Review Materials
سال: 2021
ISSN: ['2476-0455', '2475-9953']
DOI: https://doi.org/10.1103/physrevmaterials.5.094403